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Evaluation of Ozone and Ultraviolet Light
Clinton,
Massachusetts
GRAND PRIZE
— RESEARCH
ENTRANT: Black
& Veatch Corp.
ENGINEER IN CHARGE: Gerald B.
Benson, P.E., DEE
Project Role
Black & Veatch, serving as project manager and co-principal
investigator for the project, was responsible for providing overall
project management; developing the experimental test program; designing
and overseeing construction of the experimental facilities; analyzing
and evaluating data from the pilot and field studies; and developing
guidance for the industry, the Massachusetts Water Resources Authority
(MWRA) and the Town of Concord, Massachusetts.
Role of Other Consultants & Agencies
Participating Consultants
Black & Veatch assembled a unique, collaborative team for this
project, including nationally recognized experts from specific and
relevant disciplines. Robert Hulsey, Black & Veatch, and Dr. James
Malley of the University of New Hampshire served as co-principal
investigators. Dr. Malley is one of the world’s foremost researchers in
ultraviolet disinfection. Dr. Malley’s team wrote the literature review
of ultraviolet light (UV) applications for disinfection, conducted
bench-scale work with other sub-consultants, led the field challenge
trials, and performed specific analyses.
Dr. David Reckhow of the University of Massachusetts studied
disinfection by-products and performed other analyses on raw,
irradiated, and ozonated water throughout the study. Dr. Anne Camper of
Montana State University and Center for Biofilm Engineering performed
all bulk water and attached microbial analyses for the simulated
distribution system studies of ozonated and non-ozonated waters subject
to UV disinfection. Clancy Environmental of St. Albans, Vermont, and
Dr. Marilyn Marshall of the University of Arizona performed the
bench-scale Cryptosporidium inactivation work. Finally, Dr. Giovanni
Widmar of Tufts University Veterinary School, MA, performed the
bench-scale Giardia lamblia inactivation work with the University of
New Hampshire.
Other Key Participants
The active participation of water utilities and manufacturers provided
other key roles on the team. Sponsoring agency MWRA constructed and
operated the pilot facilities including raw water pumping, UV
disinfection, ozonating a portion of the water, post-treatment
corrosion control, and testing through a simulated distribution system.
MWRA collected and analyzed daily samples and helped with field trials.
Concord built and operated the full-scale one-million-gallon-per-day
ozone-UV disinfection scheme. Financial assistance and technical review
was provided by the Southern Nevada Water Authority (SNWA) and the
Portland Water Bureau, Oregon. Ozone and UV systems manufacturers
Mitsubishi Electric Power Products and Trojan Technologies donated
vital equipment. The American Water Works Association Research
Foundation (AwwaRF) directed the overall effort, providing an expert
panel to guide and review the final product.
Project Description - An Intriguing Possible Solution for an Urgent
Public Health Problem
In response to the threat of waterborne diseases caused by
Cryptosporidium, Giardia lamblia, E. coli, and other pathogens, the
U.S. Environmental Protection Agency formulated more stringent
regulations requiring a higher level of water disinfection yet lower
levels of harmful disinfection byproducts. The Interim Enhanced Surface
Water Treatment Rule requires 2 log inactivation or removal of
Cryptosporidium, a chlorine-resistant protozoan parasite. Prior
research indicated that ozone cannot cost-effectively inactivate
Cryptosporidium at cold water temperatures. Fearing a major capital
investment, water utilities nationwide sought a solution that would
enable cost-efficient compliance with the new regulations. The
combination of ozone and UV was an exciting possibility but little was
known about their interaction between the two. Credible research was
needed to determine whether the combination could inactivate target
pathogens without adversely affecting distributed water quality.
Innovative Technologies
This research was the first project to examine the sequential treatment
of raw water with ozone and UV with an emphasis on disinfection
effectiveness and disinfection byproducts. This information will be
vitally important to water professionals in reaching compliance with
emerging Stage 2 Disinfectants/Disinfection By-Product regulations.
This is the first comprehensive ozone and UV light research program in
the world for consumer water quality assessment. MWRA built the largest
ozone and ultraviolet light testing facility, while the Town of Concord
built the first full-scale system to deliver ozone+UV-treated water to
U.S. consumers. The pilot operation demonstrated process reliability
and ease of operation as well as design elements that enhanced
efficiency and effectiveness.
Also, this project was the first UV project to study distribution
system effects with seasoned, well-characterized century-old pipe loops
that are being treated with corrosion control measures and chloramines.
These pipe loops mimic the distribution system of the MWRA extremely
well from the AwwaRF Red Water Project.
Technical Value
The research provided evidence that combining the strengths of ozone
(oxidation, taste, odor reduction and virus inactivation) with UV
(Cryptosporidium inactivation) and chlorine or chloramines (bacterial
inactivation and protection within the distribution system) provided a
highly cost-effective treatment benefit. From a regulatory perspective,
ultraviolet light in concert with ozone presents a multiple
disinfection barrier approach to protecting public health.
Complexity
Increasing microbial risks in drinking water, particularly resistant
pathogens such as Giardia lamblia, Cryptosporidium, and other organisms
on the Contaminant Candidates List, dictate a growing need for
multiple-barrier disinfection. The study of multiple disinfectants,
each with distinct actions and effectiveness for specific pathogens, is
a fundamentally sound strategy because it utilizes the most
cost-effective treatment for each target organism. Results from this
project will prepare water treatment specialists for the next
millennium through heightened knowledge of multiple-barrier
disinfectant principles with ozone, UV and chloramines in a single
treatment train.
Equally important, this research demonstrates how to achieve the
conflicting and complex goals of improving disinfection without
increasing levels of halogenated disinfection byproducts or other
adverse effects on water quality in the distribution system.
Social and Economic Benefits
For MWRA and similar large unfiltered surface water systems, knowledge
gained from the study will directly impact the public, enabling
delivery of quality potable water at a reasonable cost. Placing
ultraviolet light after ozone results in capital cost savings of 19% to
21% compared to stand-alone ultraviolet light. Savings in operating
costs have also proven impressive, with 29% to 32% lower operations
costs with an optimum ozone sequence.
For water systems that rely on disinfection processes alone, the study
demonstrates how the combined benefits of ozone followed by UV
disinfection provide the most cost-effective microbial inactivation
(protozoa, bacteria and viruses) above and beyond regulatory
guidelines, thus providing a means to reach the very highest levels of
water quality.
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